DB--Choosing-the-Right-Lithium-Battery---Blog-1

Different types of lithium batteries: Choosing the right one

Posted by Matthew Campbell on Jun 6, 2023 11:00:00 AM
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Topics: Lithium

The more you know about battery performance and safety, the easier it is to select the appropriate battery from the multitude of offerings in the marketplace. Selection criteria include Battery Chemistry, Battery Management System (BMS), and Safety Certifications.

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Comparing Battery Chemistries

The following table lists some popular lithium battery chemistries with a summary of their performance, safety pros and cons, and common applications.

Table 1, Comparison of Battery Chemistries*1

 

Chemistry

Pros

Cons

Applications 

Lithium Cobalt Oxide (LCO)

  • High specific energy

  • Short lifespan (500 - 1,000 cycles)

  • Low specific power

  • Low thermal stability

Cell phones, laptops, electronic cameras

Lithium Manganese Oxide (LMO)

  • High specific power

  • Fast charging

  • High-temperature stability

  • Short lifespan (300-700 cycles)

Medical equipment, power tools, electric motorcycles, electric vehicles, laptops

Lithium Iron Phosphate (LFP)

  • Durable

  • Long lifespan (2,000+ cycles)

  • Thermal stability

  • Low specific energy

  • Poor performance in cold temperatures

e-bikes, electric vehicles, energy storage

Lithium Nickel Manganese Cobalt Oxide (NMC)

  • High specific energy density OR high specific power

  • Medium lifespan (1,000 - 2,000 cycles)

  • Thermal stability

  • Cannot have both high specific energy density and high specific power

Power tools, e-bikes, electric vehicles

Lithium Nickel Cobalt Aluminum Oxide (NCA)

  • High specific energy

  • Long lifespan

  • Low thermal stability

  • More expensive

Electric vehicles, energy storage

Lithium Titanate (LTO)

  • Rapid recharge (superior nanotechnology)

  • Long lifespan

  • Thermal stability

  • Less energy density

  • More expensive

Electric vehicles, e-bikes, military and aerospace, energy storage

 

*1 Reference information compiled from BU-216: Summary Table of Lithium-based Batteries.

Discover Batteries

While selecting the battery chemistry based on performance may be the first choice in choosing a battery for your application, battery safety has become increasingly prevalent.

For example, the car manufacturer Tesla often uses NMC or NCA batteries. However, Tesla is now adopting LFP batteries in some vehicles because thermal stability has become a higher priority.

LFP batteries, due to their safety record, are the top choice for home energy storage solutions where their high threshold for thermal runaway far outweighs their lower energy density.

However, when it comes to battery safety, it is heavily influenced by the internal or external Battery Management System (BMS).

Battery Management System

The primary job of the BMS is to deliver safety functions, including disconnecting the battery from the charging source if the battery gets too hot, too cold, or the voltage is too high. A BMS with high current ratings safely allows higher charge, discharge, and peak currents. A smart BMS communicates state-of-charge and other parameters in a closed loop with the charger. Some BMS request adjustments to the charging voltage to maximize charging speed (Dynamic Charging) while maintaining a safe battery operating temperature.

While safety is essential for consumer electronics, a low-cost mandate often means there is no BMS, and only basic cell safety protections are in place.

Safety Certification

Safety Standards

Safety Standards

Safety Standards

Safety Standards

 

Nationally Recognized Labs (NRLs) such as UL, CSA, TUV, and ETL maintain common battery safety standards for various applications. Certification by an NRL to a particular battery standard ensures that an independent third party has thoroughly tested the various safety parameters of the battery. The following are some of the more common UL battery certifications in the United States. Europe has set its own standards. Other regions may closely follow UL or European standards with modifications or set their own.

Table 1, Common Battery Safety Certifications *1

 
 

Standard

 

Description

 

UL1642

Safety certification to avoid risk of fire, explosion, and injury for battery cells that use 5.0 g or less metallic Lithium.

UL2054

Safety certification to avoid the risk of fire, explosion, and injury for a battery power source in a product.

UL9540

Safety standard for energy storage systems and equipment connecting to a power grid. This standard incorporates both UL1973 (Battery) and UL1741 (Inverter).

UL9540A

Describes thermal runaway performance of cells, modules, and battery energy storage systems.

UL1973

Standard is specific to batteries for light electric rail, stationary, and vehicle auxiliary power applications.

UL2271

Safety requirements for designing and manufacturing lithium-ion batteries used in Light Electric Vehicles (LEV), such as golf carts.

UL1741

 

Standard for inverters, converters, controllers, and interconnection system equipment connecting to the grid.

UL1741 Supplement B

Validates compliance with grid protection and grid support functions for certification as a Grid Support Utility Interactive Inverter.

IEEE 1547

Remote control of Distributed Energy Resources (DER) on the grid.

IEEE 1547-2003

Utility interconnection standard that requires DER to disconnect when a grid becomes unstable.

IEEE 1547.1-2020

Tests to validate compliance with grid interconnection and grid support features of inverters and converters.

 

*1 References:

What Do You Choose?

The more you know about battery performance and safety, the easier it is to select the appropriate battery from the multitude of offerings in the marketplace. Consult with experts when deciding which battery is right for you.